goldsquare gets The Prisoner and Firefly.
mermaidlady gets first dibs on Carnevale. She should pass it to alexx_kay once she's done; he should pass it to bleemoo, and then probably back to us to get it to alethea_eastrid.
bleemoo gets ST:TNG. (Sorry, dagonell, but that's by far the largest collection, and it's easier to give it to someone local.)
However, dagonell gets The Avengers. You should send me your postal address for shipping that.
aquamonkey gets first dibs on Babylon 5. That doesn't include Season 1 -- I can loan you that when you're ready to watch it, provided you promise to take good care of it. Once you're done, I encourage you to loan/give them to goldsquare.
alethea_eastrid gets Angel. You and msmemory should talk about which event is going to be convenient for delivering those.
Hopefully all of the tapes are in decent condition; most of them haven't been watched in a fair number of years, so I can't be certain, but I suspect they're all in at least viewable shape. I'll put together indexes of what's on each tape, for the recipients...